25/04 - 20:00
| 1965/07/04 | Atlético de Madrid |  | 1-0 |  | Real Zaragoza |
| 1st Leg | 2nd Leg | |||||||
|---|---|---|---|---|---|---|---|---|
 | (1-4) | | 1-0 | 0-4 | ||||
 | (1-2) |  | 0-2 | 1-0 | ||||
 | (4-2) |  | 4-1 | 0-1 | ||||
 | (0-2) |  | 0-0 | 0-2 | ||||
 | (2-5) |  | 2-1 | 0-4 | ||||
| (9-5) |  | 7-2 | 2-3 | ||||
 | (2-1) |  | 2-1 | 0-0 | ||||
 | (4-3) |  | 2-2 | 2-1 |
| Sporting Gijón | | (1-0) |  | Espanyol | |||||||
| 1 | 20/05 | 00:00 | Sporting Gijón | 2-1 | Espanyol | h2h | |||||
| 2 | / | : | - | h2h | |||||||
| Las Palmas | | (1-0) |  | Tenerife | |||||||
| 1 | 20/05 | 00:00 | Las Palmas | 1-0 | Tenerife | h2h | |||||
| 2 | / | : | - | h2h |
| 1st Leg | 2nd Leg | Poff | ||||||||
|---|---|---|---|---|---|---|---|---|---|---|
 | (1-2) | | 1-2 | 0-0 | ||||||
 | (1-3) | | 1-0 | 0-3 | ||||||
| (2-2) | | 2-0 | 0-2 | 0-0 | |||||
| (3-3) | | 3-1 | 0-2 | 3-3 | |||||
 | (2-3) | | 1-0 | 1-3 | ||||||
 | (5-6) | | 3-1 | 2-5 | ||||||
 | (1-4) | | 1-2 | 0-2 | ||||||
| (3-0) |  | 1-0 | 2-0 | ||||||
 | (2-7) | | 2-1 | 0-6 | ||||||
| (2-0) |  | 1-0 | 1-0 | ||||||
| (9-1) |  | 5-1 | 4-0 | ||||||
 | (1-8) | | 1-4 | 0-4 | ||||||
| (2-1) |  | 0-0 | 2-1 | ||||||
| (4-3) |  | 3-1 | 1-2 | ||||||
 | (1-6) | | 0-1 | 1-5 | ||||||
| (4-2) |  | 3-1 | 1-1 |
